Against
the backdrop of accelerating industrialization of solid-state
batteries, a solution based on novel fluorosilicone materials has drawn
industry attention today regarding the failure of encapsulation caused
by the complex chemical environment inside the battery. The newly
developed "Corrosion-Resistant Silicone Rubber Composite" successfully
solves the problem of penetration by corrosion factors such as moisture,
oxygen, and ions through unique molecular structure design, providing
critical material support for the long cycle life of high-energy-density
solid-state batteries.
According
to the R&D team, although solid-state batteries eliminate
traditional liquid electrolytes, the sulfide or oxide electrolytes used
internally can still release highly corrosive active substances under
specific conditions. Furthermore, trace amounts of acidic gases
generated during battery operation can erode traditional sealing
materials. Traditional silicone sealants are prone to main chain
scission or swelling when exposed to these corrosive media for extended
periods, leading to seal failure and subsequent battery performance
degradation or even safety hazards.
The
newly released composite uses modified polysiloxane as the matrix and
innovatively introduces fluorinated alkyl side chains and special
modified additives. During the preparation process, active groups on the
polysiloxane molecular chains undergo a grafting reaction with the
additives, forming a dense three-dimensional crosslinked network. This
network structure not only physically extends the diffusion path of
corrosive media but also utilizes the strong hydrophobicity and chemical
inertness of fluorinated alkyl groups to construct a "molecular-level
shield" on the material surface.
Experimental
data shows that after applying this material to solid-state battery
post sealing and housing encapsulation, the battery's cycle life in the
"double 85" aging test (85°C / 85% relative humidity) increased by more
than 40%. Meanwhile, in simulated electrolyte immersion tests, the
material exhibited near-zero volume swelling and effectively blocked the
erosion of strong corrosive by-products such as hydrofluoric acid.
Industry
experts point out that as solid-state batteries move from the
laboratory to mass production, the chemical stability of encapsulation
materials has become a bottleneck restricting their performance. The
emergence of this new corrosion-resistant fluorosilicone composite fills
the final gap in the solid-state battery material system. It is
expected to be incorporated into the supply chains of more battery
manufacturers starting in the second half of 2026, promoting the
commercial deployment of solid-state batteries in new energy vehicles
and energy storage fields.
IOTA MF Methylfluorosilicone oil